- Hits: 952
ICPT-AP System Realization
Anode Preparation
Chemical Formula: Ni-Ce0.8Sm0.2
Metal |
Melting point |
Density (g.cm-3) |
Nickel |
1455 oC |
8.902 |
Cerium |
795 oC |
6.76 |
Samarium |
1072 oC |
7.52 |
Total volume for 100g mass of this alloy = 13.53 cm3
Ƥ = 100/14.2 = 7.391 g/cm3
Volume of the anode (disc shape):
Radius = 6.5 cm; Height = 0.1 cm or more
V = π r2h = π*6.5*0.1 = 13.273 cm3 = 13273 mm3
- If h = 1 mm → V = 13273 mm3 = 13.273 cm3
M1 = Ƥ V = 7.391*13.273 = 98.100743 g
MNi = 286 g
MCe = 510 g
MSm = 147 g
MTotal = 286+510+147 = 943 g
Metal |
Mass (g) |
%W |
No of moles |
Xi |
Nickel |
286 |
30.33 |
4.873 |
0.5134 |
Cerium |
510 |
54.08 |
3.640 |
0.3835 |
Samarium |
147 |
15.59 |
0.978 |
0.1030 |
Alloy |
943 |
100 |
9.491 |
1 |
Procedure:
- Ni-Ce8Sm0.2 Alloy Synthesis:
Cathode Preparation
Chemical Formula: SmFe0.7Cu0.1Ni0.2
Metal
Melting point oC
Density (g.cm-3)
Samarium
1072
7.52
Iron
1538
7.874
Copper
1085
8.96
Nickel
1455
8.902
Total volume for 100g mass of this alloy = 13.01 cm3
Ƥ = 100/13.01 = 7.69 g/cm3
Volume of the cathode (disc shape):
Radius = 6.5 cm; Height = 0.1 cm
V = π r2h = π*6.5*0.1 =13.273 cm3 = 13273 mm3
If h = 1 mm → V = 13273 mm3 = 13.273 cm3
M1 = Ƥ V = 7.69*13.273 = 102.06937 g
MSm = 740.29 g
MFe = 192 g
MCu = 31.5 g
MNi = 58.5 g
MTotal = 740.29+192+31.5+58.5 = 1022.29 g
Metal
Mass (g)
%W
No of moles
Xi
Samarium
740.29
72.41
4.9235
0.5
Iron
192
18.78
3.4381
0.35
Copper
31.5
3.08
0.5
0.05
Nickel
58.5
5.72
0.9921
0.1
Alloy
1022.29
100
9.8537
1